Some Examples of Temperature and Time Resolved Studies of the Dehydration and Hydration Behavior of Zeolites and Clathrates

Depmeier, Wulf (2009) Some Examples of Temperature and Time Resolved Studies of the Dehydration and Hydration Behavior of Zeolites and Clathrates Particle & Particle Systems Characterization, 26 (3). pp. 138-150.

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Abstract

The prominent role of X-ray powder diffraction (XRPD) for the study of the dehydration and hydration behavior of microporous zeolites and clathrates can be documented by several typical examples taken from the literature. The importance of various interactions, in particular water-framework, water-extra-framework cations, framework-extra-framework cations, and water-water is discussed. However, it is emphasized that XRPD has its limitations, especially when species are disordered, and should be complemented as far as possible by the determination of bulk properties, and also by various appropriate spectroscopic methods.

Document Type: Article
Additional Information: Sp. Iss. SI501TR
Keywords: dehydrationhydration microporous temperature resolved time resolved x-ray-diffraction synchrotron powder diffraction pressure-induced hydration alpo4-15 molecular-sieve charge-density analysis crystal-structure single-crystal neutron-diffraction thermal-decomposition collapsible framework
Research affiliation: OceanRep > The Future Ocean - Cluster of Excellence
Kiel University
Refereed: Yes
ISSN: 0934-0866
Projects: Future Ocean
Date Deposited: 11 Feb 2011 12:14
Last Modified: 27 Jan 2012 05:54
URI: http://eprints.uni-kiel.de/id/eprint/9340

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