Inorganic-organic layered halide perovskites, with specific focus on PAMC, and its key and slot joint interlayers

Depmeier, Wulf (2009) Inorganic-organic layered halide perovskites, with specific focus on PAMC, and its key and slot joint interlayers Zeitschrift für Kristallographie, 224 (5-6). pp. 287-294. DOI 10.1524/zkri.2009.1134.

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Abstract

A brief account is given on layered halide perovskites A(2)BX(4), and their relationships with the 3D ABX(3) perovskites. The scientific history of the family of inorganic-organic hybrid structures of (CnH2n+1NH3)(2)MCl4, with M = Mn, Cd, Cu is described. The special case of PANIC, (C3H7NH3)(2)MnCl4, is shortly discussed, with special emphasis on the importance of non-bonded interlock layers interwoven with the topological layered perovskite structure and occurring accidentally on geometrical grounds in the propyl-compounds. These layers are believed to be the main reason for the uniqueness of these compounds in the series (CnH2n+1NH3)(2)MCl4, with n = 1 - 10 (at least). Modern achievements of investigations into other inorganic-organic hybrid perovskite-type layer structures are also addressed to.

Document Type: Article
Keywords: layered perovskitesperovskites pamc modulated phases interlock layers structural phase-transitions incommensurately modulated structure crystal neutron-diffraction x-ray-diffraction temperature phases optical-properties a2bx4 structure gamma-phase compound symmetry
Research affiliation: Kiel University
OceanRep > The Future Ocean - Cluster of Excellence
Refereed: Yes
DOI etc.: 10.1524/zkri.2009.1134
ISSN: 0044-2968
Projects: Future Ocean
Date Deposited: 11 Feb 2011 12:15
Last Modified: 22 Apr 2016 10:13
URI: http://eprints.uni-kiel.de/id/eprint/9338

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