Crystal structure of tris(N-methylsalicylaldiminato-kappa N-2,O)chromium(III)

Hilbert, Jessica, Kabus, Sven, Naether, Christian and Bensch, Wolfgang (2015) Crystal structure of tris(N-methylsalicylaldiminato-kappa N-2,O)chromium(III) Acta Crystallographica Section E-Crystallographic Communications, 71 . M247-+.

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The crystal structure of the title compound, [Cr(C8H8NO)(3)], is isotypic with the vanadium(III) analogue. The asymmetric unit consists of one Cr3+ cation and three N-methylsalicylaldiminate anions. The metal cation is octahedrally coordinated by three N,O-chelating N-methylsalicylaldiminate ligands, leading to discrete and neutral complexes. In the crystal, neighbouring complexes are linked via C-H center dot center dot center dot O hydrogen-bonding interactions into chains propagating parallel to the c axis.

Document Type: Article
Additional Information: Times Cited: 0 12
Research affiliation: OceanRep > The Future Ocean - Cluster of Excellence
Kiel University
Refereed: Yes
ISSN: 2056-9890
Projects: Future Ocean
Date Deposited: 18 Oct 2016 03:45
Last Modified: 05 Apr 2018 10:24

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