On the volume of solid solutions: an anisotropic approach

Peters, L., Knorr, K., Schmid-Beurmann, P. and Depmeier, W. (2006) On the volume of solid solutions: an anisotropic approach Physics and Chemistry of Minerals, 33 (1). pp. 10-16. DOI 10.1007/s00269-005-0057-7.

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Abstract

The dependence of the unit cell volume on intensive parameters as temperature T, pressure p, or concentration x is considered in thermodynamic calculations through bulk properties like thermal expansion, compressibility or the partial molar volume. On the other hand, crystal physics takes account of the anisotropy-inherent to crystals-and hence aims at the study of the behaviour of the individual cell parameters through a tensorial description. In this contribution, we show how the established use of the strain-tensor can be extended in order to minimize uncertainties or even fallacies in the treatment of the volume of solid solutions.

Document Type: Article
Research affiliation: Kiel University
DOI etc.: 10.1007/s00269-005-0057-7
ISSN: 0342-1791
Date Deposited: 12 Jan 2012 05:08
Last Modified: 08 Oct 2012 10:24
URI: http://eprints.uni-kiel.de/id/eprint/16014

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