Boronic Acid Flux Synthesis and Crystal Growth of Uranium and Neptunium Boronates and Borates: A Low-Temperature Route to the First Neptunium(V) Borate

Wang, S. A., Alekseev, E. V., Miller, H. M., Depmeier, W. and Albrecht-Schmitt, T. E. (2010) Boronic Acid Flux Synthesis and Crystal Growth of Uranium and Neptunium Boronates and Borates: A Low-Temperature Route to the First Neptunium(V) Borate Inorganic Chemistry, 49 (21). pp. 9755-9757. DOI 10.1021/ic101678d.

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Abstract

Molten methylboronic acid has been used as a reactive flux to prepare the first neptunium(V) borate, NpO(2)[B(3)O(4)(OH)(2)] (NpBO-1), and the first actinide boronate, UO(2)(CH(3)BO(2))(H(2)O) (UCBO-1). NpBO-1 contains cation-cation interactions between the neptunyl units. In contrast, the presence of the methyl groups in the uranyl boronate leads to a one-dimensional structure.

Document Type: Article
Keywords: structural-characterization nuclear-waste insights complex
Research affiliation: Kiel University
Refereed: Yes
DOI etc.: 10.1021/ic101678d
ISSN: 0020-1669
Date Deposited: 22 Dec 2011 05:11
Last Modified: 28 Mar 2018 10:23
URI: http://eprints.uni-kiel.de/id/eprint/15726

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