Surprising Coordination for Plutonium in the First Plutonium(III) Borate

Wang, S., Alekseev, E. V., Depmeier, W. and Albrecht-Schmitt, T. E. (2011) Surprising Coordination for Plutonium in the First Plutonium(III) Borate Inorganic Chemistry, 50 (6). pp. 2079-2081. DOI 10.1021/ic200064n.

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Abstract

The first plutonium(III) borate, Pu(2)[B(12)O(18)(OH)(4)Br(2)(H(2)O)(3)]center dot 0.5H(2)O, has been prepared by reacting plutonium(III) with molten boric add under strictly anaerobic conditions. This compound contains a three-dimensional polyborate network with triangular holes that house the plutonium(III) sites. The plutonium sites in this compound are 9- and 10-coordinate and display atypical geometries.

Document Type: Article
Keywords: fundamental building-blocks cationic framework nuclear-waste insights spectroscopy minerals complex uranium route acid
Research affiliation: Kiel University
DOI etc.: 10.1021/ic200064n
ISSN: 0020-1669
Date Deposited: 15 Dec 2011 05:19
Last Modified: 08 Oct 2012 09:27
URI: http://eprints.uni-kiel.de/id/eprint/15660

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