K(NpO(2))(3)(H(2)O)Cl(4): A Channel Structure Assembled by Two- and Three-Center Cation-Cation interactions of Neptunyl Cations

Wang, S., Alekseev, E. V., Depmeier, W. and Albrecht-Schmitt, T. E. (2011) K(NpO(2))(3)(H(2)O)Cl(4): A Channel Structure Assembled by Two- and Three-Center Cation-Cation interactions of Neptunyl Cations Inorganic Chemistry, 50 (11). pp. 4692-4694. DOI 10.1021/ic200549f.

Full text not available from this repository.

Supplementary data:

Abstract

A Np(V) compound containing three-center cation cation interations, K(NpO(2))(3)(H(2)O)Cl(4), has been prepared by reacting Np(V) with KCl in molten boric acid. This compound forms a three-dimensional channel structure that is constructed from both two- and three-center cation-cation interactions. Three new bonding modes for cation-cation interactions are added to the summary of all known Np(V) compounds.

Document Type: Article
Keywords: crystal-structure nuclear-waste complexes spectra acid actinides framework insights sulfate npo2+
Research affiliation: Kiel University
DOI etc.: 10.1021/ic200549f
ISSN: 0020-1669
Date Deposited: 15 Dec 2011 05:30
Last Modified: 08 Oct 2012 09:27
URI: http://eprints.uni-kiel.de/id/eprint/15659

Actions (login required)

View Item View Item