Alteration at the ultramafic-hosted Logatchev hydrothermal field: Constraints from trace element and Sr-O isotope data

Augustin, Nico, Paulick, H., Lackschewitz, Klas, Eisenhauer, Anton, Garbe-Schönberg, Dieter, Kuhn, Thomas, Botz, R. and Schmidt, Mark (2012) Alteration at the ultramafic-hosted Logatchev hydrothermal field: Constraints from trace element and Sr-O isotope data Geochemistry Geophysics Geosystems, 13 . QOAE07. DOI 10.1029/2011GC003903.

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Abstract

Serpentinized peridotite and gabbronorite represent the host rocks to the active, ultramafic-hosted Logatchev hydrothermal field at the Mid-Atlantic Ridge. We use trace element, δ18O and 87Sr/86Sr data from bulk rock samples and mineral separates in order to constrain the controls on the geochemical budget within the Logatchev hydrothermal system. The trace element data of serpentinized peridotite show strong compositional variations indicating a range of processes. Some peridotites experienced geochemical modifications associated with melt-rock interaction processes prior to serpentinization, which resulted in positive correlations of increasing high field strength element (HFSE) concentrations and light rare earth element (LREE) contents. Other serpentinites and lizardite mineral separates are enriched in LREE, lacking a correlation with HFSE due to interaction with high-temperature, black-smoker type fluids. The enrichment of serpentinites and lizardite separates in trace elements, as well as locally developed negative Ce-anomalies, indicate that interaction with low-T ambient seawater is another important process in the Logatchev hydrothermal system. Hence, mixing of high-T hydrothermal fluids during serpentinization and/or re-equilibration of O-isotope signatures during subsequent low-T alteration is required to explain the trace element and δ18O temperature constraints. Highly radiogenic 87Sr/86Sr signatures of serpentinite and lizardite separates provide additional evidence for interaction with seawater-derived fluids. Sparse talc alteration at the Logatchev site are most likely caused by Si-metasomatism of serpentinite associated with the emplacement of shallow gabbro intrusion(s) generating localized hydrothermal circulation. In summary the geochemistry of serpentinites from the Logatchev site document subsurface processes and the evolution of a seafloor ultramafic hydrothermal system.

Document Type: Article
Keywords: Logatchev hydrothermal field ; REE HFSE ; hydrothermal alteration ; oxygen isotopes ; serpentinites strontium isotopes
Research affiliation: Kiel University > Faculty of Mathematics and Natural Sciences > Institute of Geosciences
OceanRep > GEOMAR > FB2 Marine Biogeochemistry > FB2-MG Marine Geosystems
OceanRep > The Future Ocean - Cluster of Excellence
OceanRep > GEOMAR > FB4 Dynamics of the Ocean Floor > FB4-MUHS Magmatic and Hydrothermal Systems
Refereed: Yes
DOI etc.: 10.1029/2011GC003903
ISSN: 1525-2027
Date Deposited: 07 Sep 2012 09:00
Last Modified: 27 Feb 2017 16:43
URI: http://eprints.uni-kiel.de/id/eprint/15150

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