Impact of hot fluid advection on hydrocarbon gas production and seepage in mud volcano sediments of thick Cenozoic deltas

Nuzzo, Marianne, Elvert, Marcus, Schmidt, Mark, Scholz, Florian, Reitz, Anja, Hinrichs, Kai-Uwe and Hensen, Christian (2012) Impact of hot fluid advection on hydrocarbon gas production and seepage in mud volcano sediments of thick Cenozoic deltas Earth and Planetary Science Letters, 341-344 . pp. 139-157. DOI 10.1016/j.epsl.2012.05.009.

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Supplementary data:

Abstract

Hydrocarbon seeps are ubiquitous at gas-prone Cenozoic deltas such as the Nile Deep Sea Fan (NDSF2) where seepage into the bottom water has been observed at several mud volcanoes (MVs3) including North Alex MV (NAMV4). Here we investigated the sources of hydrocarbon gases and sedimentary organic matter together with biomarkers of microbial activity at four locations of NAMV to constrain how venting at the seafloor relates to the generation of hydrocarbon gases in deeper sediments. At the centre, high upward flux of hot (70 °C) hydrocarbon-rich fluids is indicated by an absence of biomarkers of Anaerobic Oxidation of Methane (AOM) and nearly constant methane (CH4) concentration depth-profile. The presence of lipids of incompatible thermal maturities points to mixing between early-mature petroleum and immature organic matter, indicating that shallow mud has been mobilized by the influx of deep-sourced hydrocarbon-rich fluids. Methane is enriched in the heavier isotopes, with values of δ13C∼−46.6‰VPDB and δD ∼−228‰VSMOW, and is associated with high amounts of heavier homologues (C2+) suggesting a co-genetic origin with the petroleum.

On the contrary at the periphery, a lower but sustained CH4 flux is indicated by deeper sulphate–methane transition zones and the presence of 13C-depleted biomarkers of AOM, consistent with predominantly immature organic matter. Values of δ13C-CH4∼−60‰VPDB and decreased concentrations of 13C-enriched C2+ are typical of mixed microbial CH4 and biodegraded thermogenic gas from Plio-Pleistocene reservoirs of the region. The maturity of gas condensate migrated from pre-Miocene sources into Miocene reservoirs of the Western NDSF is higher than that of the gas vented at the centre of NAMV, supporting the hypothesis that it is rather released from the degradation of oil in Neogene reservoirs. Combined with the finding of hot pore water and petroleum at the centre, our results suggest that clay mineral dehydration of Neogene sediments, which takes place posterior to reservoir filling, may contribute to intense gas generation at high sedimentation rate deltas.

Highlights

► Extensive seepage of biodegraded gas at the periphery of North Alex mud volcano.
► At the centre seepage of deeper-sourced hot water, oil and thermogenic gas.
► At the centre, degradation of reservoired-oil to gas is most likely.
► Multivariate statistics on biomarkers show oil degradation at the centre and AOM at the periphery.
► Shallow gas production is enhanced by hot water influx from actively dewatering clays.

Document Type: Article
Additional Information: WOS:000308624800014; Correction: WOS:000312621600041 EARTH AND PLANETARY SCIENCE LETTERS, 357 421-421; 10.1016/j.epsl.2012.09.026 DEC 1 2012
Keywords: Meeresgeologie; Submarine mud volcano; high sedimentation rate Cenozoic deltas; petroleum degradation; anaerobic oxidation of methane; lipid biomarkers and compound specific isotope analysis; multivariate statistical analyses; marine geosystems; GULF-OF-MEXICO; DEEP-SEA FAN; CARBON ISOTOPIC COMPOSITIONS; ANAEROBIC METHANE OXIDATION; SULFATE-REDUCING BACTERIA; ORGANIC-MATTER; MARINE-SEDIMENTS; NATURAL-GAS; NILE DELTA; COLD SEEPS
Research affiliation: OceanRep > GEOMAR > FB2 Marine Biogeochemistry > FB2-MG Marine Geosystems
OceanRep > GEOMAR > Applied R&D > Energy and CO₂ Sequestration Projects
OceanRep > The Future Ocean - Cluster of Excellence
Refereed: Yes
DOI etc.: 10.1016/j.epsl.2012.05.009
ISSN: 0012-821X
Projects: WND Project, Future Ocean
Date Deposited: 12 Jul 2012 12:28
Last Modified: 06 Mar 2017 11:03
URI: http://eprints.uni-kiel.de/id/eprint/14803

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